It's usually better to use a tone control for a push-pull, especially if you like to finely adjust the volume control - push-pulls often have fairly poor tapers when used for volumes because they're based on cheap-ish mini-pots rather than full-size ones.
The wiring is marginally neater if you use it as a volume though, since the phase switching stays on the same pot. It's also functionally nice since you almost always have to finely adjust the pickup balance when you switch to out-of-phase, to get the best result... and you've then already got the volume knob in your hand when you pull it out

.
There's also a problem in some Les Pauls with the thickness of the top in the neck volume control position which can make it hard to get a push-pull to fit there.
The actual wiring is very simple - the pot part is wired exactly as normal, and the pull-switch part is wired in the standard 'X' shape for phase switching... you just extend the lower 'legs' of the X to reach the top and ground terminals on the volume pot, and connect the pickup start and finish (red and green here) wires to the two middle terminals. If you're using the tone pot for the switch you just have to use longer wires between the two pots.